Pathway Details

Recommended name

Biosynthesis of ansamycins

Alternative names

Reactions

UDP-3-ketoglucose <-> UDP-kanosamine

UDP-kanosamine <-> Kanosamine

ATP + Kanosamine <-> ADP + Kanosamine 6-phosphate

Kanosamine 6-phosphate <-> Aminofructose 6-phosphate

D-Ribose 5-phosphate + Aminofructose 6-phosphate <-> D-Sedoheptulose 7-phosphate + Iminoerythrose 4-phosphate

Phosphoenolpyruvate + H2O + Iminoerythrose 4-phosphate <-> Phosphate + AminoDAHP

AminoDAHP <-> Phosphate + AminoDHQ

AminoDHQ <-> H2O + AminoDHS

NAD+ + UDPglucose <-> NADH + H+ + UDP-3-ketoglucose

AminoDHS <-> H2O + AHBA

Proansamycin X <-> Protorifamycin I

Protorifamycin I <-> Rifamycin W

Proansamycin X <-> Rifamycin W

Rifamycin W <-> Rifamycin B

34a-Deoxy-rifamycin W <-> Rifamycin W

Rifamycin W <-> Rifamycin W-hemiacetal

Rifamycin W <-> Rifamycin Z

Rifamycin W-hemiacetal <-> Demethyl-desacetyl-rifamycin S

Rifamycin Z <-> Demethyl-desacetyl-rifamycin S

Demethyl-desacetyl-rifamycin S <-> Demethyl-desacetyl-rifamycin SV

Demethyl-desacetyl-rifamycin SV <-> 27-O-Demethyl-rifamycin SV

27-O-Demethyl-rifamycin SV <-> Rifamycin

Rifamycin <-> Rifamycin S

Proansamycin X <-> 34a-Deoxy-rifamycin W

Rifamycin <-> Rifamycin B

NAD+ + UDP-D-glucose <-> NADH + H+ + UDP-3-ketoglucose

Classification

Metabolism of Terpenoids and Polyketides

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